Download Biocatalysis in non-conventional media : proceedings of an by J Tramper; et al PDF

By J Tramper; et al

The overseas symposium ''Fundamentals of Biocatalysis in Non-Conventional Media'' used to be equipped lower than auspices of the operating get together utilized Biocatalysis of the eu Federation of Biotechnology. one of the subject matters mentioned on the symposium have been physical-chemical facets corresponding to pH, water-activity, viscosity, dielectric constants, polarity and so forth. with regards to biocatalysis in non-conventional media. New measuring innovations have been brought. for individuals operating within the box of biocatalysis in non-conventional media this booklet will supply a great evaluate of the achieve in knowing over the past 5 years of the elemental features of biocatalysis in non-conventional media

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Read or Download Biocatalysis in non-conventional media : proceedings of an international symposium, Noordwijkerhout, 26-29 April 1992 PDF

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Extra info for Biocatalysis in non-conventional media : proceedings of an international symposium, Noordwijkerhout, 26-29 April 1992

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Seguin, M. D. Legoy and J . N. Barbotin, J . Chim. , 89 (1992) 5 4 1 . 14 C. Sarazin, G. Goethals, J . P. Seguin, M. D. Legoy and J . N. Barbotin, Ann. Ν. Y . Acad. Sei. (1992) in press. Biocatalysis in Non-Conventional Media, edited by J. Tramper et al. V. 31 All rights reserved. J. Osborne* , J . K. , V i a C r e s c e n t i n o , 13040 - S a l u g g i a ( V C ) , I t a l y 2 Hannah R e s e a r c h I n s t i t u t e , Ayr K46 5HZ UK 3 Advanced C e n t r e f o r B i o c h e m i c a l E n g i n e e r i n g , T o r r i n g t o n P l a c e , London WC1E 7 J E UK U n i v e r s i t y C o l l e g e London, The s e r i e s o f primary a l c o h o l s from methanol to o c t a n - l - o l inhibits progesterone l l a - h y d r o x y l a s e with i n c r e a s i n g potency a s t h e n o l e c u l a r weight i n c r e a s e s .

I t i s now over 90 y e a r s s i n c e Meyer & Overton proposed t h e i r r u l e t h a t " N a r c o s i s commences when any c h e m i c a l l y i n d i f f e r e n t s u b s t a n c e has a t t a i n e d a c e r t a i n molar c o n c e n t r a t i o n in the l i p o i d s o f the c e l l " . In f a c t the volume r a t i o c o r r e l a t e s b e t t e r with g e n e r a l a n a e s t h e s i a (Seeman, 1 9 7 2 ) . 1mole/kg dry membrane ( s e e T a b l e 5 in Seeman, 1 9 7 2 ) , c a u s i n g t h e i r potency to i n c r e a s e with log P»«.

3 a ) . However, the reaction rate with Accurel PA6 as support was m u c h less influenced by the water activity. At water activities above 0 . 7 , a - c h y m o t r y p s i n e x p r e s s e d m u c h h i g h e r activity w h e n 60 immobilized on Celite t h a n on the other s u p p o r t s . However, a large preportion of the enzymatic activity on Celite was due to the hydrolytic reaction, especially at high water activities (Fig. 3b). Generally, the relative alcoholysis rate decreased with increasing water activity.

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