By Arnold J. Rudolph, Arnold J. Rudol, Arnold J. Rudolph MD
Colour atlas of neonatology. quantity of a 5 quantity set masking a whole diversity of dermatologic, cardiac, pulmonary, gastrointestinal, genitourinary, neurologic, and musculoskeletal problems, genetics, and syndromes.
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Additional resources for Atlas of the Newborn. Musculoskeletal Disorders
With regard to the positionally directing electronic inﬂuence, highly electron rich moieties such as heteroaromatic rings came into consideration. Various reactions of non-radioactive nucleophiles including ﬂuoride as caesium or potassium ﬂuoride had already been carried out and showed very high regioselectivity up to regiospeciﬁcity (Yamada and Okawara 1972a, 1972b; Martin-Santamaria et al. 2000). As indicated in Table 4, radioﬂuorination via diaryliodonium salts leads mostly to both 18 F-labeled arenes in different product ratios.
4. Dependence of RCY on the number of methyl-substituents (Gail et al. 1997); trigonal bipyramidal geometry of the intermediate [18 F]ﬂuoride complex of the nucleophilic attack et al. 1997; Shah et al. 1998; Hostetler et al. 1999; Martin-Santamaria et al. 2000). With regard to the positionally directing electronic inﬂuence, highly electron rich moieties such as heteroaromatic rings came into consideration. Various reactions of non-radioactive nucleophiles including ﬂuoride as caesium or potassium ﬂuoride had already been carried out and showed very high regioselectivity up to regiospeciﬁcity (Yamada and Okawara 1972a, 1972b; Martin-Santamaria et al.
These are summarized exemplarily in Fig. 9 and in a detailed review by Okarvi (2001). In particular, reagents with ﬂuorine-18 in a stable aromatic position were of primary interest (Zalutsky et al. 1992) and, as recent examples, 4-[18 F]ﬂuorobenzaldehyde and 4-[18 F]ﬂuorophenyldiazonium have been used in chemoselective 18 F-labeling of peptides (Poethko et al. 2004; Patt et al. 2002). As very new ﬂuoroprosthetic groups for 18 F-labeling of heteropolymers such as peptides, glucoproteins and oligonucleotides, derivatized heteroarylﬂuorides (for review see Dollé 2005) and even the readily available 2-[18 F]ﬂuorodeoxyglucose (Prante et al.